Om Namo Bhagavate Vasudevaya!
The Vedic deities aren't necessarily comparable to ordinary human beings when we speak of family relationships.
A deity may appear to have parents, siblings, spouses, or children within a particular avatara-leela, but these relationships shouldn't automatically be understood as biological relationships in the ordinary material sense (e.g., the ‘births’ of the Devis Lakshmi, Saraswati, and Saraswati; Lord Brahma from Lord Vishnu; Lord Rudra from Lord Brahma; or the avataras of Lord Vishnu).
Here is an example of a Vedic deity family tree based on Gaudiya Vaishnava Siddhanta (as you can see, it is very long):
That being said, Lord Hanuman is an interesting example.
He is a deity traditionally associated with Anjana and Kesari as his parents (hence the names ‘Anjaneya’ and 'Kesari-nandan').
Lord Vayu and Lord Shiva also played important roles in his birth.
Yet Hanuman is not generally presented as having a brother or sister.
Hare Krishna